Photoinduced symmetry-breaking charge separation: the direction of the charge transfer.
نویسندگان
چکیده
Even flow: Photoinduced symmetry-breaking charge separation takes place in a few picoseconds in a 1,3-bis(perylene)propane dyad in polar solvents. Polarized transient absorption measurements show that the direction of the charge flow is random and entirely governed by the fluctuations of the solvent orientation around the dyad. MARKOVIC, Vesna, et al. Photoinduced Symmetry-Breaking Charge Separation: The Direction of the Charge Transfer. Angewandte Chemie: International Edition, 2011, vol. 50, no. 33,
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 50 33 شماره
صفحات -
تاریخ انتشار 2011